This review collectively presents the various aspects of the Zn–Fe RFB including the basic electrochemical cell chemistry of the anolyte and catholyte, and the different approaches considered for electrodes, electrolytes, membranes, and other cell components to overcome the above. . This review collectively presents the various aspects of the Zn–Fe RFB including the basic electrochemical cell chemistry of the anolyte and catholyte, and the different approaches considered for electrodes, electrolytes, membranes, and other cell components to overcome the above. . Recently, aqueous zinc–iron redox flow batteries have received great interest due to their eco-friendliness, cost-effectiveness, non-toxicity, and abundance. However, the development of zinc–iron redox flow batteries (RFBs) remains challenging due to severe inherent difficulties such as zinc. . Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical energy storage technology due to their low electrolyte cost. This review introduces the characteristics of ZIRFBs which can be operated within a wide pH range. . This comprehensive review delves into the current state of energy storage, emphasizing the technical merits and challenges associated with zinc iron flow batteries (ZIFBs).
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